I did this repair several years ago with the old ex. tank and new 0rings. Needed a bit of lube to get it to seat easily, but it has held up well.
RTV can be used just about anywhere on these cars that needs a gasket, but it is almost always preferable to use the correct gasket if one is available. I have used the orange "high temp" RTV to coat exhaust flange gaskets without issue. Rule of thumb for me is, RTV can be used to replace paper gaskets and seal metal ones, but I avoid using it on cork or neoprene, such as valve/cam cover gaskets as the thickness of these materials is generally there for a reason. The only thing to be aware of is 02 sensors and MAFs, which you may or may not have, as the wrong RTV can damage them if used in excess. There is a "sensor safe" RTV out there that supposedly will not damage them.