40 all around is a great start. It is better to be too high then too low, you don't lose as much time on the high side, the tires wear easier, and the car is more predictable.
When you feel you are ready, find a test and tune day with at most 50 cars, spend the first half of the day working on learning the course and becoming consistent, and after you can run a consistent lap, start paying attention to the car, not the driver, and then start dropping the tire pressures. Go at least 2 psi, if not 3 psi, until you get in the range. You'll have driven the course enough by then that you'll feel the difference. I like to drop both front and back evenly until I find the maximum grip, then mess with the rear tires until the car just starts to rotate without spinning. Then you may have to adjust the fronts again. Depending upon surface (and temperature for rcomps), I find the rears like 1 to 2 psi less, and once I get the rears right, I sometimes can drop both an extra psi that wouldn't work so well with equal pressures front and back.
As you get better, you get to adjust the tires again. And again. And again. Part of that is smoothing out of your driving style. The smoother you are, and the more you can anticipate the upcoming corner, the lower pressure you can run and get even more grip. It is just that lower pressures are less forgiving, so you have to be at the point that you make less mistakes (or at least smaller ones). We're not talking about much here, and shocks become very important at that time, but that's a good start.
Good luck, and may you be close to all your apexes.
-Guy