No prob...that's why you're here, to ask the experts...until one shows up I'll tell you what I know...

Spacers move the rim further out, putting far more load on the studs or lug bolts. Some spacers are plastic as well, they can deform from brake heat and cause the rims to become unbalanced. 20mm aluminum spacers are as far as I'd go. If they were steel I'd be tempted to go further.
I wouldn't even trust plastic for hub-centric rings - they allow you to properly center 4x100 pattern wheels with larger hub bores than our 57mm.
There are also adapters that bolt to the hub (4x100 pattern) and have another set of studs installed (say 4x114mm or 5x125). That allows you to use rims made for many different cars but I'd personally avoid them all. I've had rims come off cars (happily at low speeds) and it is never pretty. Getting a broken lug bolt out is an incredible PITA.