Pin 25 - output - Cyl 1 ignition coil control - that's correct. The original coils in the BMW M42 engines had a known fault where the coils would crack and therefore damage the engine ECU. I think these where on Bosch coils, which were replaced with Bremi coils. Test pin 25 for output voltage with ignition on. Should be 12V.
When looking at the coils in mounting position, pins are 1, 4a, 15. There should be 12V between pin 15 and a ground point on the vehicle, not between pin 15 and the other pins. For coil resistance, ignition must be off to check resistance. Check each coil between pin 1 & pin 15 for 0.4-0.8 ohms. You have done this correctly - so coil 1 is out of spec. Secondary resistance cannot be tested.
In the bentley manual, it also states that if there is no spark at a cylinder, check the wiring between pin 15 on the coil and the ignition switch.
Also just a heads up, be very careful when testing ignition circuits as very high voltage is present.